Fe, Ru, and Os complexes with the same molecular framework: comparison of structures, properties and catalytic activities.

نویسندگان

  • Masaki Yoshida
  • Mio Kondo
  • Masaya Okamura
  • Mari Kanaike
  • Setsiri Haesuwannakij
  • Hidehiro Sakurai
  • Shigeyuki Masaoka
چکیده

A series of group 8 metal complexes with the same molecular framework, [M(PY5Me2)L]n+ (M = Fe, Ru, and Os; PY5Me2 = 2,6-bis[1,1-bis(2-pyridyl)ethyl]pyridine; L = monodentate ligand), were successfully synthesized and structurally characterized. The spectroscopic and electrochemical properties as well as the catalytic activity for water oxidation of these complexes were investigated.

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عنوان ژورنال:
  • Faraday discussions

دوره 198  شماره 

صفحات  -

تاریخ انتشار 2017